Convenient route to tetraarylphosphonium polyelectrolytes via metal-catalysed P-C coupling polymerisation of aryl dihalides and diphenylphosphine.
نویسندگان
چکیده
A P-C bond-forming reaction has been applied to the convenient preparation of tetraarylphosphonium polyelectrolytes (TPELs) from aryl dihalides and diphenylphosphine. A TPEL having a thermal decomposition temperature of 460 °C that is also stable to heating at 65 °C in 6 M NaOH(aq) for at least 24 h has been prepared by this method.
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ورودعنوان ژورنال:
- Chemical communications
دوره 53 1 شماره
صفحات -
تاریخ انتشار 2016